Glycidyl methacrylate → Glycidyl methacrylate 1-ethoxyethyl methacrylate 2-hydroxyethyl methacrylate

HRID 1618840

반응식

HRID 1618840 반응식
[C:1]([O:6][CH2:7][CH:8]1[O:10][CH2:9]1)(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:11]([O:16][CH:17]([O:19][CH2:20][CH3:21])[CH3:18])(=[O:15])[C:12]([CH3:14])=[CH2:13].[C:22]([O:27][CH2:28][CH2:29][OH:30])(=[O:26])[C:23]([CH3:25])=[CH2:24].N(C(C)(CC)C([O-])=O)=NC(C)(CC)C([O-])=O>CCCCCCC.C(C(C)=O)C(C)C>[C:1]([O:6][CH2:7][CH:8]1[O:10][CH2:9]1)(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:11]([O:16][CH:17]([O:19][CH2:20][CH3:21])[CH3:18])(=[O:15])[C:12]([CH3:14])=[CH2:13].[C:22]([O:27][CH2:28][CH2:29][OH:30])(=[O:26])[C:23]([CH3:25])=[CH2:24]

참가 물질

7

반응물 4

HCID 7837Glycidyl methacrylateHCID 133602-Hydroxyethyl MethacrylateHCID 201933451-Ethoxyethyl Methacrylate (stabilized with MEHQ)HCID 219175032,2'-Azobis(methyl 2-methylpropanate)

생성물 1

HCID 86655548Glycidyl methacrylate 1-ethoxyethyl methacrylate 2-hydroxyethyl methacrylate

시약·촉매·용매 2

HCID 7909Methyl Isobutyl Ketone용매HCID 8900Heptane용매

실험 절차

A 500 ml three-necked flask was charged with 34.1 g (0.24 mol) of glycidyl methacrylate, 38.0 g (0.24 mol) of 1-ethoxyethyl methacrylate, 15.6 g (0.12 mol) of 2-hydroxyethyl methacrylate and 300 ml of methyl isobutyl ketone. A catalytic amount of 2,2′-azobis(methyl 2-methylpropionate) as a radical polymerization initiator was added to the mixture, and polymerization was performed in a nitrogen stream at 80° C. for six hours. The obtained reaction liquid was cooled, and poured in a large volume of heptane, thereby precipitating a polymer. The polymer crystal was collected by filtration, and dissolved in diethylene glycol dimethyl ether. The heptane and methyl isobutyl ketone contained in the solution were distilled off in vacuum, thereby obtaining a diethylene glycol dimethyl ether solution of polymer A2-5 (glycidyl methacrylate/1-ethoxyethyl methacrylate/2-hydroxyethyl methacrylate).

후처리

  1. customThe obtained reaction liquid
  2. temperaturewas cooled
  3. customprecipitating a polymer
  4. filtrationThe polymer crystal was collected by filtration
  5. dissolutiondissolved in diethylene glycol dimethyl ether
  6. distillationwere distilled off in vacuum

출처 및 근거

ORD 기록
ord-985a19afa6364699913590525c67d441
출처 데이터셋
uspto-grants-2014_07
특허 번호
US08771907B2

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