HCID 28384692, 화합물 → HCID 86628076, 화합물

반응식

Br[C:2]1[CH:3]=[C:4]([S:10]([NH:13][C:14]([CH3:17])([CH3:16])[CH3:15])(=[O:12])=[O:11])[CH:5]=[CH:6][C:7]=1[O:8][CH3:9].[CH:18]([C:20]1[CH:21]=[C:22]([CH:27]=[C:28](B2OC(C)(C)C(C)(C)O2)[C:29]=1[O:30][CH2:31]OCCOC)[C:23]([O:25][CH3:26])=[O:24])=[O:19]>>[CH2:31]([O:30][C:29]1[C:28]([C:2]2[CH:3]=[C:4]([S:10](=[O:12])(=[O:11])[NH:13][C:14]([CH3:17])([CH3:16])[CH3:15])[CH:5]=[CH:6][C:7]=2[O:8][CH3:9])=[CH:27][C:22]([C:23]([O:25][CH3:26])=[O:24])=[CH:21][C:20]=1[CH:18]=[O:19])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

참가 물질

반응물 2

HCID 28384692HCID 28384692, 화합물

HCID 86628077HCID 86628077, 화합물

생성물 1

HCID 86628076HCID 86628076, 화합물

실험 절차

Proceeding as in Reference 19, but substituting 3-bromo-N-tert-butyl-4-methoxybenzenesulfonamide and methyl 3-formyl-4-(2-methoxyethoxy-methoxy)-5-(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)-benzoate, gave methyl 6-benzyloxy-5′-tert-butylsulfamoyl-5-formyl-2′-methoxy-biphenyl-3-carboxylate.

출처 및 근거

ORD 기록: ord-2b369b8cc08342f4bd275f95f277aec2
출처 데이터셋: uspto-grants-2014_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08778625B2

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