Estragole → HCID 68316885, 화합물

반응식

[CH2:1]([C:4]1[CH:9]=[CH:8][C:7]([O:10][CH3:11])=[CH:6][CH:5]=1)[CH:2]=[CH2:3].[C:12]([O:16][CH:17]1[CH:24]2[CH2:25][CH:20]3[CH2:21][CH:22]([CH2:26][CH:18]1[CH2:19]3)[CH2:23]2)(=[O:15])C=C>>[CH3:11][O:10][C:7]1[CH:8]=[CH:9][C:4]([CH2:1]/[CH:2]=[CH:3]/[C:12]([O:16][CH:17]2[CH:18]3[CH2:26][CH:22]4[CH2:21][CH:20]([CH2:25][CH:24]2[CH2:23]4)[CH2:19]3)=[O:15])=[CH:5][CH:6]=1

참가 물질

반응물 2

HCID 8815Estragole

HCID 112986972-Adamantyl acrylate

생성물 1

HCID 68316885HCID 68316885, 화합물수율 82.1%

실험 절차

The representative procedure was followed using 4-allylanisole (74 mg, 0.50 mmol), 2-adamantyl acrylate (206 mg, 1.00 mmol) and Grubbs-2 catalyst (8.5 mg, 0.01 mmol). Column chromatography on silica gel (eluting with 5% EtOAc/hexanes) afforded the product as a colorless oil (134 mg, 82%).

출처 및 근거

ORD 기록: ord-d5113c8c7fa64780a7c2e6ed5f893471
출처 데이터셋: uspto-grants-2014_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08785665B2

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