Diethyl P-((methylthio)methyl)phosphonate → HCID 23002059, 화합물

반응식

CS[CH2:3][P:4](=[O:11])([O:8][CH2:9][CH3:10])[O:5][CH2:6][CH3:7].C[O-:13].[Na+].CO>>[CH2:6]([O:5][P:4]([CH:3]=[O:13])([O:8][CH2:9][CH3:10])=[O:11])[CH3:7]

참가 물질

반응물 2

HCID 520377Diethyl P-((methylthio)methyl)phosphonate

HCID 23694274Sodium methanolate methanol

생성물 1

HCID 23002059HCID 23002059, 화합물

실험 절차

Oxydation of diethyl methylthiomethylphosphonate include anodic oxidation in NaOMe/MeOH (saturated with CO2) to give the O, S-acetal of diethoxyphosphinylformaldehyde, which upon oxidation may give the corresponding sulfone as Diethyl methoxy(methylsulfone)phenyl phosphonate (Shankaran, K et al. 2001).

출처 및 근거

ORD 기록: ord-d569afd160224dd8ae3fec41d4c23359
출처 데이터셋: uspto-grants-2014_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08791235B2

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