HCID 21719419, 화합물 → 2-(2-Methoxyethoxy)benzene-1-sulfonyl isocyanate

HRID 1633196노트

반응식

HRID 1633196 반응식
[CH3:1][O:2][CH2:3][CH2:4][O:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][C:7]=1[S:12]([NH:15][C:16](NC)=[O:17])(=[O:14])=[O:13]>ClC1C=CC=CC=1>[CH3:1][O:2][CH2:3][CH2:4][O:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][C:7]=1[S:12]([N:15]=[C:16]=[O:17])(=[O:14])=[O:13]

참가 물질

3

반응물 1

HCID 21719419HCID 21719419, 화합물

생성물 1

HCID 204396542-(2-Methoxyethoxy)benzene-1-sulfonyl isocyanate수율 99.1%

시약·촉매·용매 1

HCID 7964Chlorobenzene용매

실험 절차

13.0 g of N-(2-methoxyethoxy-phenylsulfonyl)-N'-methylurea are suspended in 200 ml of chlorobenzene. The solution is dried by azeotropic destillation of about 20 ml of the solvent. 7.0 g of phosgen are introduced into the solution within 45 minutes at a temperature of the reaction mixture to dryness yields 11.5 g of 2-methoxyethoxy-phenylsulfonyl-isocyanate in form of a yellowish oil.

후처리

  1. dry with materialThe solution is dried by azeotropic destillation of about 20 ml of the solvent
  2. addition7.0 g of phosgen are introduced into the solution within 45 minutes at a temperature of the reaction mixture to dryness

출처 및 근거

ORD 기록
ord-9d70075564c34e939863e0b3bb8ad55f
출처 데이터셋
uspto-grants-1984_10
특허 번호
US04479821

반응 노트

불러오는 중…