1-Bromodecane → (4-Decyloxyphenyl)phenyliodonium tosylate

HRID 1638967노트

반응식

HRID 1638967 반응식
F[Sb-](F)(F)(F)(F)F.[CH2:8]([O:18][C:19]1[CH:24]=[CH:23][C:22]([I+:25][C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)=[CH:21][CH:20]=1)[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17].BrCCCCCCCCCC.C1(OCCCCCCCCCC)C=CC=CC=1.[S:60]([C:72]1[CH:78]=[CH:77][C:75]([CH3:76])=[CH:74][CH:73]=1)([O:63][IH](C1C=CC=CC=1)=O)(=[O:62])=[O:61]>ClCCl.C(O)(=O)C>[S:60]([C:72]1[CH:78]=[CH:77][C:75]([CH3:76])=[CH:74][CH:73]=1)([O-:63])(=[O:62])=[O:61].[CH2:8]([O:18][C:19]1[CH:24]=[CH:23][C:22]([I+:25][C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)=[CH:21][CH:20]=1)[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17]

참가 물질

7

반응물 4

HCID 81731-BromodecaneHCID 520713Decyloxybenzene2회HCID 16687828(4-Decyloxyphenyl)phenyliodonium hexafluoroantimonateHCID 178427798HCID 178427798, 화합물

생성물 1

HCID 86743519(4-Decyloxyphenyl)phenyliodonium tosylate수율 67.5%

시약·촉매·용매 2

HCID 176Acetic Acid용매HCID 6344Dichloromethane용매

실험 절차

The procedure of Example 1 was repeated to prepare (4-decyloxyphenyl)phenyliodonium hexafluoroantimonate. 1-bromodecane was used and the yield of decyl phenyl ether was 98.9%. In accordance with Example 1, 196 grams (0.5 mol) of phenyliodoso tosylate, 117 grams (0.5 mol) of the decyl phenyl ether, 50 ml of acetic acid and 200 ml of dichloromethane were stirred at 40° C. for 2 hours. The reaction mixture was filtered and a solution triturated with ether. The crystallized product was isolated by suction filtration and washed with ether and then dried under vacuum. There was obtained, 205.3 grams (67.5% yield of (4-decyloxyphenyl)phenyliodonium tosylate.

후처리

  1. filtrationThe reaction mixture was filtered
  2. customa solution triturated with ether
  3. customThe crystallized product was isolated by suction filtration
  4. washwashed with ether
  5. customdried under vacuum
  6. customThere was obtained

출처 및 근거

ORD 기록
ord-d4316c3d2adf41ca86364c29c40e2dd5
출처 데이터셋
uspto-grants-1989_11
특허 번호
US04882201

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