3-Isopropoxy-4-nitrotoluene → 4-Methyl-2-(propan-2-yloxy)aniline

HRID 1639116노트

반응식

HRID 1639116 반응식
[CH3:1][C:2]1[CH:3]=[CH:4][C:5]([N+:12]([O-])=O)=[C:6]([O:8][CH:9]([CH3:11])[CH3:10])[CH:7]=1.[H][H]>CO.[Pd]>[CH3:1][C:2]1[CH:3]=[CH:4][C:5]([NH2:12])=[C:6]([O:8][CH:9]([CH3:11])[CH3:10])[CH:7]=1

참가 물질

5

반응물 2

HCID 5927313-Isopropoxy-4-nitrotolueneHCID 178418361HCID 178418361, 화합물2회

생성물 1

HCID 150681144-Methyl-2-(propan-2-yloxy)aniline

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 887Methanol용매

실험 절차

5-Methyl-1-(1-methylethoxy)-2-nitrobenzene, 17.7 g (91 mmol), is dissolved in methanol, palladium on charcoal is added and the mixture is exposed to hydrogen gas until the required amount of hydrogen is absorbed. The mixture is worked up in the usual manner to give 15 g of 4-methyl-2-(1-methylethoxy)benzenamine.

후처리

  1. customis absorbed

출처 및 근거

ORD 기록
ord-3e627e157205460095844073242a2bc9
출처 데이터셋
uspto-grants-1989_11
특허 번호
US04882357

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