1,1,3,3-Tetramethyldisilazane, 97% → HCID 59227480, 화합물

반응식

[C:1]1([C:7]#[C:8][CH2:9][OH:10])[CH2:6][CH2:5][CH2:4][CH2:3][CH:2]=1.[CH3:11][SiH:12]([CH3:17])N[SiH](C)C>>[C:1]1([C:7]#[C:8][CH2:9][O:10][SiH:12]([CH3:17])[CH3:11])[CH2:6][CH2:5][CH2:4][CH2:3][CH:2]=1

참가 물질

반응물 2

HCID 851961,1,3,3-Tetramethyldisilazane, 97%

HCID 127701823-(Cyclohex-1-en-1-yl)prop-2-yn-1-ol

생성물 1

HCID 59227480HCID 59227480, 화합물수율 176%

실험 절차

3-Cyclohexenylprop-2-yn-1-ol (2.509 g, 26.10 mmol) and 1,1,3,3-tetramethyldisilazane (1.527 g, 11.45 mmol) were used according to the method mentioned above to produce the title compound as a brown clear liquid (3.916 g, 20.15 mmol, 77.2%). The crude reaction mixture was analyzed by 1H NMR to confirm the product formation and used in KOtBu catalyzed transhydrosilylation reaction.

출처 및 근거

ORD 기록: ord-dc702f953bd54bcdb9d2ccfc24939a18
출처 데이터셋: uspto-grants-2012_02
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08110695B2

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