N,N-bis(1H-benzimidazol-2-ylmethyl)-N-benzylamine chromium (III) chloride → N,N-bis(1H-benzimidazol-2-ylmethyl)-N-benzylamine chromium (III) chloride hexafluoroantimonate tetrahydrofuran

HRID 1645213노트

반응식

HRID 1645213 반응식
[O:1]1[CH2:5][CH2:4][CH2:3][CH2:2]1.[F:6][Sb-:7]([F:12])([F:11])([F:10])([F:9])[F:8].[Cl-:13].[Cr+3:14].N1C2C=CC=CC=2N=C1CNCC1NC2C=CC=CC=2N=1.[Cl-].[Cr+3].[NH:38]1[C:42]2[CH:43]=[CH:44][CH:45]=[CH:46][C:41]=2[N:40]=[C:39]1[CH2:47][N:48]([CH2:56][C:57]1[NH:61][C:60]2[CH:62]=[CH:63][CH:64]=[CH:65][C:59]=2[N:58]=1)[CH2:49][C:50]1[CH:55]=[CH:54][CH:53]=[CH:52][CH:51]=1.[Cl-].[Cl-]>F[Sb-](F)(F)(F)(F)F.[Ag+]>[O:1]1[CH2:5][CH2:4][CH2:3][CH2:2]1.[F:6][Sb-:7]([F:12])([F:11])([F:10])([F:9])[F:8].[Cl-:13].[Cr+3:14].[NH:38]1[C:42]2[CH:43]=[CH:44][CH:45]=[CH:46][C:41]=2[N:40]=[C:39]1[CH2:47][N:48]([CH2:56][C:57]1[NH:58][C:59]2[CH:65]=[CH:64][CH:63]=[CH:62][C:60]=2[N:61]=1)[CH2:49][C:50]1[CH:55]=[CH:54][CH:53]=[CH:52][CH:51]=1

참가 물질

4

반응물 2

HCID 86638462N,N-bis(1H-benzimidazol-2-ylmethyl)-N-benzylamine chromium (III) chlorideHCID 86638469N,N-bis(1H-benzimidazol-2-ylmethyl)amine chromium (III) chloride hexafluoroantimonate tetrahydrofuran

생성물 1

HCID 86638470N,N-bis(1H-benzimidazol-2-ylmethyl)-N-benzylamine chromium (III) chloride hexafluoroantimonate tetrahydrofuran

시약·촉매·용매 1

HCID 16687962Silver hexafluoroantimonate촉매

실험 절차

4d was synthesised by an analogous procedure to that described for 4a using silver hexafluoroantimonate (0.20 g, 0.57 mmol) and complex 3d (0.30 g, 0.57 mmol). Yield 0.31 g, 68%. +FAB-MS: (m/e): 489 ([M]+), 454 ([M-Cl]+). −FAB-MS: (m/z): 235 ([M]−).

출처 및 근거

ORD 기록
ord-a1b2b7bf60704172a50648da50812bc5
출처 데이터셋
uspto-grants-2012_02
특허 번호
US08124698B2

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