N,N-bis(1H-benzimidazol-2-ylmethyl)amine chromium (III) chloride hexafluoroantimonate tetrahydrofuran → N,N-bis(1H-benzimidazol-2-ylmethyl)-N-methylamine chromium (III) chloride hexafluoroantimonate tetrahydrofuran

HRID 1645214노트

반응식

HRID 1645214 반응식
[O:1]1[CH2:5][CH2:4][CH2:3][CH2:2]1.[F:6][Sb-:7]([F:12])([F:11])([F:10])([F:9])[F:8].[Cl-:13].[Cr+3:14].N1C2C=CC=CC=2N=C1CNCC1NC2C=CC=CC=2N=1.[Cl-].[Cr+3].[NH:38]1[C:42]2[CH:43]=[CH:44][CH:45]=[CH:46][C:41]=2[N:40]=[C:39]1[CH2:47][N:48]([CH2:55][C:56]1[NH:60][C:59]2[CH:61]=[CH:62][CH:63]=[CH:64][C:58]=2[N:57]=1)[CH2:49]CCCCC.[Cl-].[Cl-]>F[Sb-](F)(F)(F)(F)F.[Ag+].C1COCC1>[O:1]1[CH2:5][CH2:4][CH2:3][CH2:2]1.[F:6][Sb-:7]([F:12])([F:11])([F:10])([F:9])[F:8].[Cl-:13].[Cr+3:14].[NH:38]1[C:42]2[CH:43]=[CH:44][CH:45]=[CH:46][C:41]=2[N:40]=[C:39]1[CH2:47][N:48]([CH2:55][C:56]1[NH:57][C:58]2[CH:64]=[CH:63][CH:62]=[CH:61][C:59]=2[N:60]=1)[CH3:49]

참가 물질

5

반응물 2

HCID 86638469N,N-bis(1H-benzimidazol-2-ylmethyl)amine chromium (III) chloride hexafluoroantimonate tetrahydrofuranHCID 86638471N,N-bis(1H-benzimidazol-2-ylmethyl)-N-hexylamine chromium (III) chloride

생성물 1

HCID 86638468N,N-bis(1H-benzimidazol-2-ylmethyl)-N-methylamine chromium (III) chloride hexafluoroantimonate tetrahydrofuran

시약·촉매·용매 2

HCID 16687962Silver hexafluoroantimonate촉매HCID 8028Tetrahydrofuran용매

실험 절차

4b was synthesised by an analogous procedure to that described for 4a using silver hexafluoroantimonate (0.661 g, 1.92 mmol) and complex 3e (1 g, 1.92 mmol). Yield 1.32 g, 87%. +FAB-MS: (m/e): 483 ([M]+), 467 ([M-Me]+), 449 ([M-Cl]), 361 ([M-Cr, Cl, THF). −FAB-MS: (m/z): 235 ([M]−).

출처 및 근거

ORD 기록
ord-6a647d4d20a84b88be9115cbd47872ea
출처 데이터셋
uspto-grants-2012_02
특허 번호
US08124698B2

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