Dichlorodimethylsilane → 2,2-Dimethyl-1,3-dioxa-2-sila-4-thiacyclohexane-4,4-dioxide

반응식

Cl[Si:2](Cl)([CH3:4])[CH3:3].[Na+].[S:7]([CH2:11][CH2:12][OH:13])([O-:10])(=[O:9])=[O:8]>>[CH3:3][Si:2]1([CH3:4])[O:10][S:7](=[O:9])(=[O:8])[CH2:11][CH2:12][O:13]1

참가 물질

반응물 2

HCID 6398Dichlorodimethylsilane

HCID 517063Sodium Isethionate

생성물 1

HCID 577755092,2-Dimethyl-1,3-dioxa-2-sila-4-thiacyclohexane-4,4-dioxide수율 67%

실험 절차

To 25 mL of dichlorodimethylsilane in a 100 mL r.b. flask was added 10 g of isethionic acid sodium salt and the mixture was heated to reflux with stirring for 20 hrs. The excess dichlorodimethylsilane was distilled and the residue transferred to a short-path distillation tube with a CH2Cl2 rinse. The residue was distilled at 145-175° C., 0.2 mm pressure, to give 8.25 g (67%) of a viscous liquid.

후처리

temperaturethe mixture was heated
temperatureto reflux
distillationThe excess dichlorodimethylsilane was distilled
customthe residue transferred to a short-path distillation tube with a CH2Cl2
washrinse
distillationThe residue was distilled at 145-175° C.

출처 및 근거

ORD 기록: ord-4f9d5988257847c4a8a85b9ff7a6a35a
출처 데이터셋: uspto-grants-2012_02
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08124793B2

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