Glycolic Acid → Formate

HRID 1646712

반응식

HRID 1646712 반응식
[C:1]([OH:5])(=[O:4])[CH2:2][OH:3].CC1ONC(=[O:10])C=1CC(N)[C:15]([OH:17])=[O:16]>>[C:1]([O-:5])(=[O:4])[CH:2]=[O:3].[CH:15]([O-:17])=[O:16].[C:2]([O-:10])(=[O:3])[C:1]([O-:5])=[O:4]

참가 물질

5

반응물 2

HCID 757Glycolic Acid2회HCID 1221alpha-AMINO-3-HYDROXY-5-METHYL-4-ISOXAZOLEPROPIONIC ACID

생성물 3

HCID 283FormateHCID 71081OxalateHCID 3614358Npc324351

실험 절차

The enzymatic oxidation of glycolic acid in Example 5 was repeated at pH 8.5, and using initial concentrations of glycolic acid and AMPA of 0.50M and 0.40M, respectively. After 16.5 h, the HPLC yields of glyoxylate, formate, and oxalate were 85.4%, 3.5%, and 6.3%, respectively, and 1.4% glycolate remained. The final pH of the reaction mixture was 7.0.

출처 및 근거

ORD 기록
ord-cac0e7d3df57469ca85c8d9671964b52
출처 데이터셋
uspto-grants-1993_01
특허 번호
US05180846

연결된 노트

불러오는 중…