tert-Butyl 4-benzoylbenzene-1-carboperoxoate → Tert-butyl-4-(4'-methoxybenzoyl)perbenzoate

HRID 1649334노트

반응식

HRID 1649334 반응식
[C:1]([O:5][O:6][C:7](=[O:22])[C:8]1[CH:13]=[CH:12][C:11]([C:14](=[O:21])[C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[CH:10][CH:9]=1)([CH3:4])([CH3:3])[CH3:2].[CH3:23][O:24]C1C=CC(C(C2C=CC(C(O)=O)=CC=2)=O)=CC=1>CCOCC.ClCCl>[C:1]([O:5][O:6][C:7](=[O:22])[C:8]1[CH:13]=[CH:12][C:11]([C:14](=[O:21])[C:15]2[CH:20]=[CH:19][C:18]([O:24][CH3:23])=[CH:17][CH:16]=2)=[CH:10][CH:9]=1)([CH3:4])([CH3:2])[CH3:3]

참가 물질

5

반응물 2

HCID 13494638tert-Butyl 4-benzoylbenzene-1-carboperoxoateHCID 177891814-(4-Methoxybenzoyl)benzoic acid

생성물 1

HCID 20427249Tert-butyl-4-(4'-methoxybenzoyl)perbenzoate

시약·촉매·용매 2

HCID 3283Diethyl Ether용매HCID 6344Dichloromethane용매

실험 절차

Tert-butyl-4-(4'-methoxybenzoyl)perbenzoate is prepared by the above discussed procedure for the preparation of t-butyl-4-benzoylperbenzoate, except that the acid employed is 4-(4'-methoxybenzoyl)-benzoic acid, and during the preparation, the corresponding acid chloride is dissolved in a mixture of ether and dichloromethane.

후처리

  1. customduring the preparation

출처 및 근거

ORD 기록
ord-42394d99e7b444b48082b6568f0c284f
출처 데이터셋
uspto-grants-1983_11
특허 번호
US04416826

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