HCID 12507348, 화합물 → HCID 57108974, 화합물

HRID 1651437노트

반응식

ClC1(Cl)[C@@H]2[C@@H](CCC=C2)C1=O.[CH3:12][O:13][C@@:14]12[C:21](=[O:22])[CH2:20][C@@H:19]1[CH:18]=[CH:17][CH2:16][CH2:15]2>>[CH3:12][O:13][C@:14]12[C:21](=[O:22])[CH2:20][C@H:19]1[CH:18]=[CH:17][CH2:16][CH2:15]2

참가 물질

반응물 2

HCID 12507348HCID 12507348, 화합물

HCID 54568732HCID 54568732, 화합물

생성물 1

HCID 57108974HCID 57108974, 화합물

실험 절차

Similarly, starting with (1S,6R)-8,8-dichlorobicyclo[4.2.0]oct-2-en-7-one in place of the racemic compound in Preparation 3.A. above, (1S,6S)-6-methoxybicyclo[4.2.0]oct-2-en-7-one is prepared. Similarly, starting with the (1R,6S)-compound, (1R,6R)-6-methoxybicyclo[4.2.0]oct-2-en-7-one is prepared.

후처리

customis prepared

출처 및 근거

ORD 기록: ord-0b9c6e2d1a4e4040a81e95f498699d95
출처 데이터셋: uspto-grants-1990_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04927963

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