Water → HCID 11183541, 화합물

HRID 1654451노트

반응식

HRID 1654451 반응식
[Cl:1][C:2]1[CH:13]=[C:12]([Cl:14])[CH:11]=[CH:10][C:3]=1[O:4][CH2:5][CH2:6][C:7]([OH:9])=O.O=P12OP3(OP(OP(O3)(O1)=O)(=O)O2)=O.O>CS(O)(=O)=O>[Cl:14][C:12]1[CH:13]=[C:2]([Cl:1])[C:3]2[O:4][CH2:5][CH2:6][C:7](=[O:9])[C:10]=2[CH:11]=1

참가 물질

5

반응물 3

HCID 962WaterHCID 14812Phosphorus oxide (P4O10)HCID 1190483-(2,4-Dichlorophenoxy)propanoic acid

생성물 1

HCID 11183541HCID 11183541, 화합물수율 0.1%

시약·촉매·용매 1

HCID 6395Methanesulfonic Acid용매

실험 절차

3-(2,4-Dichlorophenoxy)propionic acid (52.36 g,0 223 mol) is added portion-wise to a mixture of phosphorus pentoxide (70.98 g, 0.490 mol) in methanesulfonic acid (Eaton's reagent) under nitrogen. The reaction mixture is stirred at room temperature for 4 hours, poured into water and filtered to obtain a solid. The solid is washed with water and dried in a vacuum oven to give the title product as an off-white solid (45.88 g, mp 86°-87° C.).

후처리

  1. filtrationfiltered
  2. customto obtain a solid
  3. washThe solid is washed with water
  4. customdried in a vacuum oven

출처 및 근거

ORD 기록
ord-9f38dc5817c042eb9f0816a285fc2bab
출처 데이터셋
uspto-grants-1995_04
특허 번호
US05407897

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