Sodium Iodide → HCID 54271327, 화합물

HRID 1655994노트

반응식

HRID 1655994 반응식
[CH3:1][Si:2]([CH3:13])([CH2:9][CH2:10][CH2:11]Cl)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[I-:14].[Na+]>CC(C)=O>[CH3:1][Si:2]([CH3:13])([CH2:9][CH2:10][CH2:11][I:14])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

참가 물질

4

반응물 2

HCID 5238Sodium IodideHCID 12446004(3-Chloropropyl)(dimethyl)phenylsilane

생성물 1

HCID 54271327HCID 54271327, 화합물

시약·촉매·용매 1

HCID 180Acetone용매

실험 절차

Dimethyl(3-chloropropyl)phenylsilane [J. W. Wilt, W. K. Chwang, C. F. Dockus and N. M. Tomiuk, J. Am. Chem. Soc., 100, 5534, (1978)] (9 g, 48.8 mmol) and sodium iodide (29.5 g, 195 mmol) are refluxed in acetone during 24 hours. The mixture is filtered and the solvent is evaporated under reduced pressure. The residue is dissolved in diethyl ether and washed with water. The organic layer is dried with sodium sulfate, filtered and concentrated under reduced pressure to afford pure dimethyl(3-iodopropyl)phenylsilane as a slightly yellow oil (12.5 g, 93%).

후처리

  1. filtrationThe mixture is filtered
  2. customthe solvent is evaporated under reduced pressure
  3. dissolutionThe residue is dissolved in diethyl ether
  4. washwashed with water
  5. dry with materialThe organic layer is dried with sodium sulfate
  6. filtrationfiltered
  7. concentrationconcentrated under reduced pressure

출처 및 근거

ORD 기록
ord-f6db99b6098344adb2f9018a0b2b87ff
출처 데이터셋
uspto-grants-1993_10
특허 번호
US05252587

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