Ethyl isocyanate → 4-Ethylcarbamoyl-2,2,7,7-tetramethyl-1,4diazacycloheptan-5-one

반응식

[CH3:1][C:2]1([CH3:12])[CH2:8][NH:7][C:6](=[O:9])[CH2:5][C:4]([CH3:11])([CH3:10])[NH:3]1.[CH2:13]([N:15]=[C:16]=[O:17])[CH3:14]>>[CH2:13]([NH:15][C:16]([N:7]1[C:6](=[O:9])[CH2:5][C:4]([CH3:11])([CH3:10])[NH:3][C:2]([CH3:12])([CH3:1])[CH2:8]1)=[O:17])[CH3:14]

참가 물질

반응물 2

HCID 8022Ethyl isocyanate

HCID 5469102,2,7,7-Tetramethyl-1,4-diazepan-5-one

생성물 1

HCID 215303134-Ethylcarbamoyl-2,2,7,7-tetramethyl-1,4diazacycloheptan-5-one

실험 절차

Using the same conditions as in Example 4, 17 parts of 2,2,7,7 -tetramethyl-1,4-diazacycloheptan-5-one and 8 parts of ethylisocyanate afforded an almost colourless oil which was distilled in vacuo to yield 20 parts of 4-ethylcarbamoyl-2,2,7,7-tetramethyl-1,4diazacycloheptan-5-one of boiling point 103° - 107°C at 1mm pressure. This material gave the following elemental analysis by weight:

후처리

customafforded an almost colourless oil which
distillationwas distilled in vacuo

출처 및 근거

ORD 기록: ord-992dc168fcac4870988c862fcd1390e6
출처 데이터셋: uspto-grants-1976_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US03962255

반응 노트

불러오는 중…