HCID 4163245, 화합물 → N-Phenethyl-benzene-1,4-diamine

HRID 1658447노트

반응식

HRID 1658447 반응식
[C:1]1([CH2:7][CH2:8][NH:9][C:10]2[CH:15]=[CH:14][C:13]([N+:16]([O-])=O)=[CH:12][CH:11]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[H][H]>[Pd].CO>[C:1]1([CH2:7][CH2:8][NH:9][C:10]2[CH:11]=[CH:12][C:13]([NH2:16])=[CH:14][CH:15]=2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

참가 물질

5

반응물 2

HCID 4163245HCID 4163245, 화합물HCID 178418361HCID 178418361, 화합물2회

생성물 1

HCID 2316538N-Phenethyl-benzene-1,4-diamine

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 887Methanol용매

실험 절차

A mixture of 15 g. of N-(2-phenylethyl)-p-nitroaniline, 100 ml. of methanol, and 2.5 g. of 10% palladium on carbon catalyst is shaken under 1 to 2 atmospheres of hydrogen until uptake of the hydrogen ceases. The resultant reaction mixture is filtered through celite and washed with methanol. The filtrate is concentrated in vacuo to yield the product, N-(2-phenylethyl)-p-phenylenediamine, as an oil which can be converted to the dihydrochloride, m.p. 247°C. by bubbling hydrogen chloride gas through a solution of the oil in ether for 1/2 hour.

후처리

  1. additionA mixture of 15 g
  2. customThe resultant reaction mixture
  3. filtrationis filtered through celite
  4. washwashed with methanol
  5. concentrationThe filtrate is concentrated in vacuo

출처 및 근거

ORD 기록
ord-dcc239e5b37b435fb91370e08c32847e
출처 데이터셋
uspto-grants-1976_06
특허 번호
US03963780

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