Benzene → Acetyl chloride, 2,2'-[1,2-phenylenebis(oxy)]bis-

HRID 1658914노트

반응식

HRID 1658914 반응식
[C:1]([Cl:6])(=[O:5])[C:2](Cl)=[O:3].[CH:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1>>[Cl:6][C:1]([CH2:2][O:3][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][C:8]=1[O:3][CH2:2][C:1]([Cl:6])=[O:5])=[O:5]

참가 물질

3

반응물 2

HCID 241BenzeneHCID 65578Oxalyl chloride

생성물 1

HCID 11076276Acetyl chloride, 2,2'-[1,2-phenylenebis(oxy)]bis-

실험 절차

30 g. Of the above acid are added to a mixture of 200 ml. anhydrous benzene. Then 35 g. oxalylchloride are added, the flask being protected by a calcium chloride tube. The mixture is stirred for four days and the diacid progressively dissolves as it is being transformed into the corresponding dichloride. The solution is then evaporated to dryness (without heating) leaving a brownish solid residue which is recrystallized from a mixture of chloroform-benzene giving white crystals.

후처리

  1. additionOf the above acid are added to a mixture of 200 ml
  2. customthe flask being protected by a calcium chloride tube
  3. customThe solution is then evaporated to dryness (without heating)
  4. customleaving a brownish solid residue which
  5. customis recrystallized from a mixture of chloroform-benzene giving white crystals

출처 및 근거

ORD 기록
ord-e8269324f1e94e6aa493aaf3bff55fa8
출처 데이터셋
uspto-grants-1976_06
특허 번호
US03966766

반응 노트

불러오는 중…