Bromotriphenylmethane → 1-Bromo-5,5-dimethyl-3-triphenylmethoxy-trans-1-octene

HRID 1659055

반응식

HRID 1659055 반응식
[Br:1]/[CH:2]=[CH:3]/[CH:4]([OH:12])[CH2:5][C:6]([CH3:11])([CH3:10])[CH2:7][CH2:8][CH3:9].[C:13]1([C:19](Br)([C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)[C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>>[Br:1]/[CH:2]=[CH:3]/[CH:4]([O:12][C:19]([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)([C:26]1[CH:27]=[CH:28][CH:29]=[CH:30][CH:31]=1)[C:20]1[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1)[CH2:5][C:6]([CH3:11])([CH3:10])[CH2:7][CH2:8][CH3:9]

참가 물질

3

반응물 2

HCID 11692BromotriphenylmethaneHCID 204657501-Bromo-5,5-dimethyl-trans-1-octen-3-ol

생성물 1

HCID 204656921-Bromo-5,5-dimethyl-3-triphenylmethoxy-trans-1-octene

실험 절차

Treatment of 3.53 g. (15 moles) of 1-bromo-5,5-dimethyl-trans-1-octen-3-ol (Example 1177) with 4.85 g. (15 moles) of triphenylmethyl bromide in 35 ml. of pyridine and purification on Florisil, all as described in Example 728 gives the title compound.

후처리

  1. customof pyridine and purification on Florisil

출처 및 근거

ORD 기록
ord-7c113086c8e640b1b15c73fd8c51771d
출처 데이터셋
uspto-grants-1976_06
특허 번호
US03966773

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