Water → Methyl octyl sulfide

HRID 1659447노트

반응식

HRID 1659447 반응식
[CH3:1][S:2]SC.[CH2:5]=[CH:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].O.C(OCC)C>C(#N)C>[CH3:1][S:2][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

참가 물질

6

반응물 4

HCID 962WaterHCID 3283Diethyl EtherHCID 81251-OcteneHCID 12232Dimethyl Disulfide

생성물 1

HCID 77289Methyl octyl sulfide수율 64.8%

시약·촉매·용매 1

HCID 6342Acetonitrile용매

실험 절차

The procedure of Example 1 was repeated using dimethyldisulphide (96 mg; 1.02 mmol) and 1-octene (358 mg; 3.19 mmol) in acetonitrile (15 ml) at +1.20 V until 2 coulomb equivalents of charge had been passed. After the addition of water and extraction with diethyl ether, there was obtained 106 mg of methylthio-octane. Mass Spec. m/e 217 (M+) and 44 (100%). I.R. 3300 and 1650 cm-1.

후처리

  1. additionof charge

출처 및 근거

ORD 기록
ord-4412bfae539948fd8cc68a4008a25a58
출처 데이터셋
uspto-grants-1981_12
특허 번호
US04304642

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