Aluminum ethylate → 3-Phenoxybenzyl alcohol

HRID 1659650노트

반응식

HRID 1659650 반응식
[O:1]([C:8]1[CH:9]=[C:10]([CH:13]=[CH:14][CH:15]=1)[CH:11]=[O:12])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[O-]CC.[Al+3].[O-]CC.[O-]CC>C(O)C>[O:1]([C:8]1[CH:9]=[C:10]([CH:13]=[CH:14][CH:15]=1)[CH2:11][OH:12])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

참가 물질

4

반응물 2

HCID 11153Aluminum ethylateHCID 382843-Phenoxybenzaldehyde

생성물 1

HCID 262953-Phenoxybenzyl alcohol수율 98.9%

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

To a solution of 198 g. of m-phenoxy-benzaldehyde in 1 liter of absolute ethanol 60 g. of aluminum ethoxide are added. The reaction mixture is allowed to stand at room temperature. The reaction mixture is then evaporated under atmospheric pressure. From the residue following the procedure of Example 1 198 g. (98.9%) of m-phenoxybenzyl alcohol are prepared in a purity over 95% (according to gas chromatography).

후처리

  1. customto stand at room temperature
  2. customThe reaction mixture is then evaporated under atmospheric pressure

출처 및 근거

ORD 기록
ord-ac39fed2a49f4867aa4db807882f9c9d
출처 데이터셋
uspto-grants-1981_12
특허 번호
US04304938

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