N-Methyl-2,6-dinitroaniline → N2-Methylbenzene-1,2,3-triamine

HRID 1665220

반응식

HRID 1665220 반응식
[CH3:1][NH:2][C:3]1[C:8]([N+:9]([O-])=O)=[CH:7][CH:6]=[CH:5][C:4]=1[N+:12]([O-])=O>O1CCCC1.[Pd]>[CH3:1][NH:2][C:3]1[C:8]([NH2:9])=[CH:7][CH:6]=[CH:5][C:4]=1[NH2:12]

참가 물질

4

반응물 1

HCID 80010N-Methyl-2,6-dinitroaniline

생성물 1

HCID 12296380N2-Methylbenzene-1,2,3-triamine수율 99%

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 8028Tetrahydrofuran용매

실험 절차

To a suspension of N-methyl-2,6-dinitroaniline (407 mg, 2.06 mmol) in tetrahydrofuran (6.5 mL) was added palladium on carbon (45 mg), and the mixture was purged with hydrogen and stirred under balloon pressure hydrogen for 5 hr at room temperature. The catalyst was removed by filtration, and the filtrate was concentrated in vacuo to give the title compound (280 mg, 2.04 mmol, 99%) as an oil.

후처리

  1. customthe mixture was purged with hydrogen
  2. customThe catalyst was removed by filtration
  3. concentrationthe filtrate was concentrated in vacuo

출처 및 근거

ORD 기록
ord-1ef500cda2824b619f923d67c0127569
출처 데이터셋
uspto-grants-2011_10
특허 번호
US08039500B2

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