HCID 178447907, 화합물 → HCID 178447906, 화합물

HRID 1671545

반응식

HRID 1671545 반응식
[N+:1]([C:4]1[CH:71]=[CH:70][C:7]([CH2:8][C:9]([CH2:60][C:61]2[CH:66]=[CH:65][C:64]([N+:67]([O-])=O)=[CH:63][CH:62]=2)([CH2:36][C:37](=[O:59])[CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][O:43][C:44]2[CH:49]=[CH:48][C:47]([C@H:50]3[CH2:55][CH2:54][C@H:53]([CH2:56][CH2:57][CH3:58])[CH2:52][CH2:51]3)=[CH:46][CH:45]=2)[C:10]([C:13](=[O:35])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][O:19][C:20]2[CH:25]=[CH:24][C:23]([C@H:26]3[CH2:31][CH2:30][C@H:29]([CH2:32][CH2:33][CH3:34])[CH2:28][CH2:27]3)=[CH:22][CH:21]=2)([OH:12])[OH:11])=[CH:6][CH:5]=1)([O-])=O>[Zn]>[NH2:1][C:4]1[CH:5]=[CH:6][C:7]([CH2:8][C:9]([CH2:60][C:61]2[CH:66]=[CH:65][C:64]([NH2:67])=[CH:63][CH:62]=2)([CH2:36][C:37](=[O:59])[CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][O:43][C:44]2[CH:45]=[CH:46][C:47]([C@H:50]3[CH2:51][CH2:52][C@H:53]([CH2:56][CH2:57][CH3:58])[CH2:54][CH2:55]3)=[CH:48][CH:49]=2)[C:10]([C:13](=[O:35])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][O:19][C:20]2[CH:25]=[CH:24][C:23]([C@H:26]3[CH2:27][CH2:28][C@H:29]([CH2:32][CH2:33][CH3:34])[CH2:30][CH2:31]3)=[CH:22][CH:21]=2)([OH:11])[OH:12])=[CH:70][CH:71]=1

참가 물질

3

반응물 1

HCID 178447907HCID 178447907, 화합물

생성물 1

HCID 178447906HCID 178447906, 화합물

시약·촉매·용매 1

HCID 23994Zinc촉매

실험 절차

Preparation can be carried out analogously to Synthetic Example 1 using 0.975 g (1.00 mmol) 2,2-bis(4-nitrobenzyl)-1,3-di{6-[4-(trans-4-propylcyclohexyl) phenoxy]hexanoyl}propanediol, 1.62 g (6.00 mmol) Ferric chloride hexahydrate and 0.65 g (10.00 mmol) Zinc powder yield 2,2-bis(4 -aminobenzyl)-1,3-di{6-[4-(trans-4-propylcyclohexyl)phenoxy]hexanoyl}propanediol.

후처리

  1. customPreparation

출처 및 근거

ORD 기록
ord-74343d710a95492c9900e96c96cc42f0
출처 데이터셋
uspto-grants-2011_08
특허 번호
US07994273B2

연결된 노트

불러오는 중…