Acetic Acid → Acetic acid, 2-(4-nitrophenyl)hydrazide

HRID 1679246노트

반응식

HRID 1679246 반응식
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([NH:10][NH2:11])=[CH:6][CH:5]=1)([O-:3])=[O:2].[C:12](O)(=[O:14])[CH3:13]>>[C:12]([NH:11][NH:10][C:7]1[CH:6]=[CH:5][C:4]([N+:1]([O-:3])=[O:2])=[CH:9][CH:8]=1)(=[O:14])[CH3:13]

참가 물질

3

반응물 2

HCID 176Acetic AcidHCID 3310889(4-Nitrophenyl)hydrazine

생성물 1

HCID 3404344Acetic acid, 2-(4-nitrophenyl)hydrazide

반응 조건

온도
90 °C

실험 절차

4-Nitrophenylhydrazine (15.0 g, 0.10 mole) and acetic acid (24.0 g, 0.40 mole) were mixed in a flask equipped with a stirrer and reflux condenser and heated at about 90° C for one hour. The solid mass was collected, washed with water, and then dissolved in hot ethanol. The resulting solution was chilled in ice to give tan needles. Yield 14.4 g (74%), mp 207°-209° C.

후처리

  1. customequipped with a stirrer
  2. temperaturereflux condenser
  3. customThe solid mass was collected
  4. washwashed with water
  5. dissolutiondissolved in hot ethanol
  6. temperatureThe resulting solution was chilled in ice
  7. customto give tan needles

출처 및 근거

ORD 기록
ord-dfa883a8947146d0a3519bd8d60be686
출처 데이터셋
uspto-grants-1978_03
특허 번호
US04080207

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