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llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
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Sodium Iodide → HCID 20362960, 화합물

HRID 1679502
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HRID 1679502 반응식
CCCCN1C(=O)N(CCCC)C(=O)C(=C/C=C/C=C2/N(CCCS([O-])(=O)=O)C3C(O/2)=CC=CC=3)C1=O.[Na+].[CH2:39]([N:41]1[C:45](=[O:46])[C:44](=[C:47](Cl)[CH:48]=[C:49]2[N:53]([CH2:54][CH3:55])[C:52]3[CH:56]=[CH:57][CH:58]=[CH:59][C:51]=3[S:50]2)[S:43][C:42]1=[S:61])[CH3:40].C(#N)C.[I-].[Na+]>C(N(CC)CC)C>[CH2:39]([N:41]1[C:45](=[O:46])[C:44](=[C:47]=[C:48]=[C:49]2[N:53]([CH2:54][CH3:55])[C:52]3[CH:56]=[CH:57][CH:58]=[CH:59][C:51]=3[S:50]2)[S:43][C:42]1=[S:61])[CH3:40]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

6

반응물 4

HCID 5238Sodium IodideHCID 6342AcetonitrileHCID 23678802Merocyanine IHCID 73676526HCID 73676526, 화합물

생성물 1

HCID 20362960HCID 20362960, 화합물

시약·촉매·용매 1

HCID 8471Triethylamine용매

실험 절차

A mixture of the merocyanine dye of Example 9 (1 g), acetonitrile (100 ml), sodium iodide (5 g) and triethylamine (7 ml) are heated at reflux with stirring for 1 minute and chilled immediately. The dye is collected and washed sequentially with acetonitrile, water, acetonitrile and ether. After recrystallization from acetonitrile, the yield of purified dye is 0.57 g (63%).

후처리

  1. temperatureare heated
  2. temperatureat reflux
  3. temperaturechilled immediately
  4. customThe dye is collected
  5. washwashed sequentially with acetonitrile, water, acetonitrile and ether
  6. customAfter recrystallization from acetonitrile

출처 및 근거

ORD 기록
ord-8d859434ac214aac848119351b3d6eff
출처 데이터셋
uspto-grants-1978_03
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04080496

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