Pyridinium chloride → 2,2,3-Trimethyl-5-hydroxy-6,7-dichloro1-indanone

반응식

[CH3:1][C:2]1([CH3:17])[CH:10]([CH3:11])[C:9]2[C:4](=[C:5]([Cl:15])[C:6]([Cl:14])=[C:7]([O:12]C)[CH:8]=2)[C:3]1=[O:16].Cl.N1C=CC=CC=1>>[CH3:17][C:2]1([CH3:1])[CH:10]([CH3:11])[C:9]2[C:4](=[C:5]([Cl:15])[C:6]([Cl:14])=[C:7]([OH:12])[CH:8]=2)[C:3]1=[O:16]

참가 물질

반응물 2

HCID 10176127Pyridinium chloride

HCID 203584512,2,3-Trimethyl-5-methoxy-6,7-dichloro-1-indanone

생성물 1

HCID 203584682,2,3-Trimethyl-5-hydroxy-6,7-dichloro1-indanone

실험 절차

By following the procedure described in Example 7, Step B, using as the reactants 2,2,3-trimethyl-5-methoxy-6,7-dichloro-1-indanone (10 g.) and pyridine hydrochloride (100 g.), there is obtained 2,2,3-trimethyl-5-hydroxy-6,7-dichloro1-indanone.

출처 및 근거

ORD 기록: ord-ac9391457af9420180f4e473bf9ca725
출처 데이터셋: uspto-grants-1978_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04081554

반응 노트

불러오는 중…