HCID 20231523, 화합물 → HCID 20231522, 화합물

반응식

NC(CCCCCCCCC(N)C(C)C)C(C)C.C(C1CC=CCCC=CCC(C(C)C)N=N1)(C)C.[CH:37]1([CH:43]2[CH2:54][CH:53]=[CH:52][CH2:51][CH2:50][CH:49]=[CH:48][CH2:47][CH:46]([CH:55]3[CH2:60][CH2:59][CH2:58][CH2:57][CH2:56]3)[N:45]=[N:44]2)[CH2:42][CH2:41][CH2:40][CH2:39][CH2:38]1>>[NH2:44][CH:43]([CH:37]1[CH2:42][CH2:41][CH2:40][CH2:39][CH2:38]1)[CH2:54][CH2:53][CH2:52][CH2:51][CH2:50][CH2:49][CH2:48][CH2:47][CH:46]([NH2:45])[CH:55]1[CH2:60][CH2:59][CH2:58][CH2:57][CH2:56]1

참가 물질

반응물 3

HCID 20231523HCID 20231523, 화합물

HCID 56630335HCID 56630335, 화합물

HCID 56635899HCID 56635899, 화합물

생성물 1

HCID 20231522HCID 20231522, 화합물수율 90.3%

실험 절차

If there are used in the manner described under (a), instead of 250 g (1 mol) of 3,12-diisopropyl-1,2-diaza- 1,5,9-cyclododecatriene, 328.5 g (1 mol) of 3,12-dicyclohexyl-1,2-diaza-1,5,9-cyclododecatriene (diastereoisomeric mixture) and correspondingly reduced amounts of catalyst and solvent, with otherwise the same procedure, there is obtained, as the main fraction, 304 g (90% of theory) of 1,10-diamino-1,10-dicyclohexyldecane in the form of colourless oil [b.p. 190°-193° C./0.05 Torr; nD20 =1.4944; IR (liquid) inter alia bands at 3355, 3278 and 1613 cm-1 ].