HCID 20231523, 화합물 → HCID 20231521, 화합물

HRID 1680727노트

반응식

NC(CCCCCCCCC(N)C(C)C)C(C)C.C(C1CC=CCCC=CCC(C(C)C)N=N1)(C)C.[CH3:37][CH:38]([CH:41]1[CH2:52][CH:51]=[CH:50][CH2:49][CH2:48][CH:47]=[CH:46][CH2:45][CH:44]([CH:53]([CH2:55][CH3:56])[CH3:54])[N:43]=[N:42]1)[CH2:39][CH3:40]>>[NH2:42][CH:41]([CH2:52][CH2:51][CH2:50][CH2:49][CH2:48][CH2:47][CH2:46][CH2:45][CH:44]([NH2:43])[CH:53]([CH3:54])[CH2:55][CH3:56])[CH:38]([CH3:37])[CH2:39][CH3:40]

참가 물질

반응물 3

HCID 20231523HCID 20231523, 화합물

HCID 56628760HCID 56628760, 화합물

HCID 56635899HCID 56635899, 화합물

생성물 1

HCID 20231521HCID 20231521, 화합물수율 85%

실험 절차

If there are used in the manner described under (a), instead of 250 g (1 mol) of 3,12-diisopropyl-1,2-diaza-1,5,9-cyclododecatriene, 87.3 g (0.31 mol) of 3,12-di-(2-butyl)-1,2-diaza-1,5,9-cyclododecatriene (diastereoisomeric mixture) and correspondingly reduced amounts of catalyst and solvent, with otherwise the same procedure, there is obtained, as the main fraction, 74.7 g (85% of theory) of 4,13-diamino-3,14-dimethylhexadecane in the form of colourless oil [b.p. 143°-5° C./0.05 Torr; nD20 =1.4639; IR (liquid) inter alia bands at 3330 and 1626 cm-1 ].

출처 및 근거

ORD 기록: ord-6014d4c29e5a4e3f8dc20f6068792b32
출처 데이터셋: uspto-grants-1981_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04275239

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