1,1'-Thiocarbonyldiimidazole → HCID 20454059, 화합물

반응식

[CH:1]([NH:3][NH:4][C:5]1[CH:10]=[CH:9][C:8]([NH:11][C:12](N(CC2C=CC=CC=2)CC2C=CC=CC=2)=[S:13])=[CH:7][CH:6]=1)=[O:2].[C:29](NNC1C=CC(N)=CC=1)(=O)C.C(N1C=CN=C1)(N1C=CN=C1)=S>>[C:1]([NH:3][NH:4][C:5]1[CH:10]=[CH:9][C:8]([N:11]=[C:12]=[S:13])=[CH:7][CH:6]=1)(=[O:2])[CH3:29]

참가 물질

반응물 3

HCID 802641,1'-Thiocarbonyldiimidazole

HCID 81068Acetic acid, 2-(4-aminophenyl)hydrazide

HCID 23454956HCID 23454956, 화합물

생성물 1

HCID 20454059HCID 20454059, 화합물

실험 절차

4-(2-Acetylhydrazino)phenyl isothiocyanate was prepared as described for NA-11 in Example 4 with 1-acetyl-2-(4-aminophenyl)hydrazine (1.23 g, 0.0075 mole) and 1,1'-thiocarbonyldiimidazole (1.35 g, 0.0075 mole). Yield 1.20 g (77 percent), m.p. 172°-174° C.

출처 및 근거

ORD 기록: ord-a5acd6a6acba45bf8b94e6f4a43edd0d
출처 데이터셋: uspto-grants-1981_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04276364

반응 노트

불러오는 중…