Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium Hydroxide → 9,9-Bis(4-pyridinylmethyl)-2-methylfluorene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | 2-Methylfluorene | HCID 15026 | — |
| 반응물 | 4-(Chloromethyl)pyridinium chloride | HCID 74570 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | 9,9-Bis(4-pyridinylmethyl)-2-methylfluorene | HCID 14941570 | — |
반응 단계
The title compound was prepared following the procedure of Example 5 from 0.95 g of 2-methylfluorene, 2.17 g of 4-picolylchloride hydrochloride, 50 mg of cetyl(Bu)3PBr, 30 ml toluene, and 5 ml 50% NaOH by reaction at 50° for 6 hrs. The material was chromatographed to yield 0.2 g product. NMR (CDCl3,200 MHz) δ: 2.47(s,3H), 3.37(s,4H), 6.49(d,J=5.3Hz,4H), 7.03-7.45(arom.H), 8.09(d,4H). HRMS calculated for C26H22N2 : 362.1783 Found: 362.1778
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05173489 |
| 출처 데이터셋 | uspto-grants-1992_12 |
| ORD ID | ord-40f6d4028eef4bc38ed7a35c1fadc4b3 |
| 출처 메모 | uspto-grants-1992_12 |