Benzyl Bromide → Methylsulfinylmethylbenzylmethyl sulfonium bromide

HRID 1684263노트

반응식

HRID 1684263 반응식
C[CH:2]([S:6][CH:7](S(C)=O)[CH3:8])[S:3]([CH3:5])=[O:4].C([Br:19])[C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>>[Br-:19].[CH3:5][S:3]([CH2:2][SH+:6][CH2:7][CH2:8][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)=[O:4]

참가 물질

3

반응물 2

HCID 7498Benzyl BromideHCID 54140058Methylmethylsulfinylmethyl sulfide

생성물 1

HCID 86750971Methylsulfinylmethylbenzylmethyl sulfonium bromide수율 26%

실험 절차

6.21 g of methylmethylsulfinylmethyl sulfide and 17.10 g of benzyl bromide were mixed, and were then allowed to stand in reaction at 50° C. for five months. The compound obtained was washed with ether, dried at 40° C. under reduced pressure, affording a precursor, methylsulfinylmethylbenzylmethyl sulfonium bromide. Yield: 26%.

후처리

  1. customto stand in reaction at 50° C. for five months
  2. customThe compound obtained
  3. washwas washed with ether
  4. customdried at 40° C. under reduced pressure

출처 및 근거

ORD 기록
ord-7da4a01399a347dda8cd25e19cffa251
출처 데이터셋
uspto-grants-1997_06
특허 번호
US05639903

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