Diisobutylaluminumhydride → (2S,4R)-5-benzyloxy-2-(tert-butoxycarbonyl)amino-4-methylpentanoic acid methyl ester

반응식

[C:1]([O:5][C:6]([NH:8][C@@H:9]([CH2:22][C@H:23]([CH2:27][O:28][CH2:29][C:30]1[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=1)[CH:24](C)C)[C@@H:10]([OH:21])CC(=C)C(NCCCC)=O)=[O:7])([CH3:4])([CH3:3])[CH3:2].[C:36]([O:40][C:41]([NH:43][C@@H:44]([CH2:57][C@H:58]([CH2:62][O:63][CH2:64][C:65]1[CH:70]=[CH:69][CH:68]=[CH:67][CH:66]=1)[CH:59](C)C)[C@H:45]([OH:56])CC(=C)C(NCCCC)=O)=[O:42])([CH3:39])([CH3:38])[CH3:37].[H-].C([Al+]CC(C)C)C(C)C>C1(C)C=CC=CC=1>[CH3:36][O:40][C:10](=[O:21])[C@@H:9]([NH:8][C:6]([O:5][C:1]([CH3:2])([CH3:3])[CH3:4])=[O:7])[CH2:22][C@@H:23]([CH3:24])[CH2:27][O:28][CH2:29][C:30]1[CH:31]=[CH:32][CH:33]=[CH:34][CH:35]=1.[CH2:64]([O:63][CH2:62][C@H:58]([CH3:59])[CH2:57][C@H:44]([NH:43][C:41]([O:40][C:36]([CH3:39])([CH3:38])[CH3:37])=[O:42])[CH:45]=[O:56])[C:65]1[CH:66]=[CH:67][CH:68]=[CH:69][CH:70]=1