Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → Benzaldehyde, 2,6-dichloro-, oxime
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | 2,6-Dichlorobenzaldehyde | HCID 6737 | — |
| 반응물 | Triethylamine | HCID 8471 | — |
| 반응물 | Hydroxyamine hydrochloride | HCID 443297 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | Benzaldehyde, 2,6-dichloro-, oxime | HCID 91328 | 132.9% |
반응 단계
Alternate procedure: Add triethylamine (23.1 g, 229 mmol) dropwise to a solution of 2,6-dichloro-benzaldehyde (20.0 g, 114 mmol) and hydroxylamine hydrochloride (10.3 g, 149 mmol) in dichloromethane (200 mL). Stir the reaction mixture for 8 h. Add water (200 mL). Separate the phases and extract the aqueous phase with dichloromethane (100 mL). Wash the combined organic phases with water (100 mL). Concentrate the combined organic phases to provide 28.8 g (94%) of the title compound.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08153624B2 |
| 출처 데이터셋 | uspto-grants-2012_04 |
| ORD ID | ord-868f23b784d94cea9d97e1fd57aa73cf |
| 출처 메모 | uspto-grants-2012_04 |