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HCID 18319637, 화합물 → HCID 18319549, 화합물

HRID 1699377
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인쇄 미리보기

반응식

HRID 1699377 반응식
[OH:1][CH2:2][C:3]1[C:13]2[O:12][CH2:11][CH2:10][C:9]([C:14]([O:16][CH2:17][CH3:18])=[O:15])=[CH:8][C:7]=2[CH:6]=[CH:5][CH:4]=1>[O-2].[Mn+4].[O-2]>[CH:2]([C:3]1[C:13]2[O:12][CH2:11][CH2:10][C:9]([C:14]([O:16][CH2:17][CH3:18])=[O:15])=[CH:8][C:7]=2[CH:6]=[CH:5][CH:4]=1)=[O:1]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

3

반응물 1

HCID 18319637HCID 18319637, 화합물

생성물 1

HCID 18319549HCID 18319549, 화합물수율 96.3%

시약·촉매·용매 1

HCID 178418406HCID 178418406, 화합물촉매

실험 절차

A mixture of ethyl 2,3-dihydro-9-hydroxymethyl-1-benzoxepin-4-carboxylate (0.45 g) and manganese (IV) oxide (4.5 g) was stirred under reflux for 1 hour and filtered off. The filtrate was evaporated in vacuo to give a solid of ethyl 2,3-dihydro-9-formyl-1-benzoxepin-4-carboxylate (0.43 g).

후처리

  1. temperatureunder reflux for 1 hour
  2. filtrationfiltered off
  3. customThe filtrate was evaporated in vacuo

출처 및 근거

ORD 기록
ord-6af95d4826784047ac077d193790cff0
출처 데이터셋
uspto-grants-2002_02
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US06346527B1

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