HCID 11109189, 화합물 → HCID 11065720, 화합물

반응식

[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH:8]1[CH2:13][C:12](=[O:14])[CH:11]=[C:10]([S:15][CH2:16][C:17](=O)[CH3:18])[CH2:9]1>C1(C)C(C)=CC=CC=1>[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH:8]1[CH2:13][C:12](=[O:14])[C:11]2[C:17]([CH3:18])=[CH:16][S:15][C:10]=2[CH2:9]1

참가 물질

실험 절차

A solution of 5-(2-chlorophenyl)-3-(2-oxopropylthio)-2-cyclohexen-1-one (1.0 g) in xylene (10 ml) was refluxed for 7.5 days and cooled, and the reaction solution was purified with silica gel column chromatography (EtOAc/hexane) to give oil of 6-(2-chlorophenyl)-3-methyl-4,5,6,7-tetrahydrobenzothiophene-4-one (0.07 g).

후처리

temperaturecooled
customthe reaction solution was purified with silica gel column chromatography (EtOAc/hexane)

출처 및 근거

ORD 기록: ord-4e522adf603a4af88e33087f0c6a68c1
출처 데이터셋: uspto-grants-2002_02
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06350749B1

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참가 물질

반응물 1

HCID 11109189HCID 11109189, 화합물

생성물 1

HCID 11065720HCID 11065720, 화합물수율 7.5%

시약·촉매·용매 1

HCID 7237O-Xylene용매

실험 절차

후처리

temperaturecooled
customthe reaction solution was purified with silica gel column chromatography (EtOAc/hexane)

출처 및 근거

ORD 기록: ord-4e522adf603a4af88e33087f0c6a68c1
출처 데이터셋: uspto-grants-2002_02
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06350749B1

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불러오는 중…