HCID 12923316, 화합물 → 2-Methyl-3-tert.-butoxypropan-1-ol

반응식

[C:1]([O:5][CH2:6][CH:7]([CH3:15])[C:8](OC(C)(C)C)=[O:9])([CH3:4])([CH3:3])[CH3:2].[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[C:1]([O:5][CH2:6][CH:7]([CH3:15])[CH2:8][OH:9])([CH3:4])([CH3:3])[CH3:2]

참가 물질

반응물 2

HCID 12923316HCID 12923316, 화합물

HCID 21226445Aluminium lithium hydride

생성물 1

HCID 125367792-Methyl-3-tert.-butoxypropan-1-ol수율 88%

실험 절차

Reduction of rac.-tert. butyl 3-tert.butoxy-2-methylpropionate was carried out with lithium aluminum hydride using the procedure described in Example 2. The resulting rac.-3-tert. butoxy-2-methyl-1-propanol was obtained in 88% yield as a colorless liquid, b.p. 70°-72° C. (10 mm Hg.).

출처 및 근거

ORD 기록: ord-8ede9dc7dd02442c8cc61b630dfe8d69
출처 데이터셋: uspto-grants-1980_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04191842

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