Thionyl Chloride → HCID 20534493, 화합물

HRID 1701355노트

반응식

HRID 1701355 반응식
[Cl:1][C:2]1[CH:19]=[CH:18][C:5]([C:6]([C:8]2[C:9]([CH3:17])=[C:10]([CH:14]=[CH:15][CH:16]=2)[C:11](O)=[O:12])=[O:7])=[CH:4][CH:3]=1.S(Cl)([Cl:22])=O>>[Cl:1][C:2]1[CH:19]=[CH:18][C:5]([C:6]([C:8]2[C:9]([CH3:17])=[C:10]([CH:14]=[CH:15][CH:16]=2)[C:11]([Cl:22])=[O:12])=[O:7])=[CH:4][CH:3]=1

참가 물질

3

반응물 2

HCID 24386Thionyl ChlorideHCID 21432883HCID 21432883, 화합물

생성물 1

HCID 20534493HCID 20534493, 화합물

실험 절차

A mixture of 29.9 g of 3-p-chlorobenzoyl-2-methyl-benzoic acid and 300 cc of thionyl chloride was refluxed for 3 hours and then stirred at room temperature overnight. Excess thionyl chloride was removed under reduced pressure and the last traces were eliminated by adding benzene and distilling the benzene off under reduced pressure to obtain 3-p-chlorobenzoyl-2-methyl-benzoyl chloride.

후처리

  1. temperaturewas refluxed for 3 hours
  2. customExcess thionyl chloride was removed under reduced pressure
  3. additionby adding benzene
  4. distillationdistilling the benzene off under reduced pressure

출처 및 근거

ORD 기록
ord-c0d9795c03b14561b39c3ba6f2b40839
출처 데이터셋
uspto-grants-1980_03
특허 번호
US04192890

반응 노트

불러오는 중…