HCID 15610185, 화합물 → 5,14-Diaminooctadecane

HRID 1701771노트

반응식

HRID 1701771 반응식
NC(CCCCCCCCC(N)CCC)CCC.C(C1CC=CCCC=CCC(CCC)N=N1)CC.[CH2:37]([CH:41]1[CH2:52][CH:51]=[CH:50][CH2:49][CH2:48][CH:47]=[CH:46][CH2:45][CH:44]([CH2:53][CH2:54][CH2:55][CH3:56])[N:43]=[N:42]1)[CH2:38][CH2:39][CH3:40]>>[NH2:42][CH:41]([CH2:52][CH2:51][CH2:50][CH2:49][CH2:48][CH2:47][CH2:46][CH2:45][CH:44]([NH2:43])[CH2:53][CH2:54][CH2:55][CH3:56])[CH2:37][CH2:38][CH2:39][CH3:40]

참가 물질

4

반응물 3

HCID 15610185HCID 15610185, 화합물HCID 56615476HCID 56615476, 화합물HCID 571937833,12-Dibutyl-1,2-diaza-1,5,9-cyclododecatriene

생성물 1

HCID 205590315,14-Diaminooctadecane수율 62.3%

실험 절차

If there is used in the manner described under (a), instead of 942 g (3.79 mols), of 3,12-dipropyl-1,2-diaza-1,5,9-cyclododecatriene, 208 g (0.75 mol) of 3,12-dibutyl-1,2-diaza-1,5,9-cyclododecatriene (diastereoisomeric mixture) and correspondingly reduced amounts of catalyst and solvent, the procedure otherwise being the same, there is obtained as the main fraction 132.8 g (62.3% of theory) of 5,14-diaminooctadecane as colourless oil (b.p. 149° C./0.001 Torr; nD20 =1.4593; IR (liquid) inter alia bands at 3333, 3267 and 1613 cm-1).

출처 및 근거

ORD 기록
ord-9807105283ca41d083aa5598e6f7276e
출처 데이터셋
uspto-grants-1980_03
특허 번호
US04195165

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