Perfluorooctanesulfonic acid → HCID 88746277, 화합물

HRID 1702959

반응식

HRID 1702959 반응식
[CH3:1][NH:2][CH:3]([C:5]1[CH:10]=[CH:9][C:8]([CH:11]([CH3:13])[CH3:12])=[CH:7][CH:6]=1)[CH3:4].[F:14][C:15]([F:42])([S:38]([OH:41])(=[O:40])=[O:39])[C:16]([F:37])([F:36])[C:17]([F:35])([F:34])[C:18]([F:33])([F:32])[C:19]([F:31])([F:30])[C:20]([F:29])([F:28])[C:21]([F:27])([F:26])[C:22]([F:25])([F:24])[F:23]>C(O)C>[F:42][C:15]([F:14])([S:38]([O-:41])(=[O:40])=[O:39])[C:16]([F:36])([F:37])[C:17]([F:35])([F:34])[C:18]([F:32])([F:33])[C:19]([F:31])([F:30])[C:20]([F:29])([F:28])[C:21]([F:27])([F:26])[C:22]([F:25])([F:24])[F:23].[CH3:1][NH2+:2][CH:3]([C:5]1[CH:6]=[CH:7][C:8]([CH:11]([CH3:13])[CH3:12])=[CH:9][CH:10]=1)[CH3:4]

참가 물질

4

반응물 2

HCID 74483Perfluorooctanesulfonic acidHCID 20120487N-methyl-1-(4-isopropylphenyl) ethylamine

생성물 1

HCID 88746277HCID 88746277, 화합물

시약·촉매·용매 1

HCID 702Ethanol용매2회

실험 절차

The perfluoro-octyl sulphonate salt was prepared by mixing a solution of N-methyl-1-(4-isopropylphenyl) ethylamine (17.6 g) in ethanol (20 ml) with a solution of perfluoro-octylsulphonic acid (50 g) in ethanol (150 ml). The ethanol solution was evaporated under reduced pressure and the solid residue was recrystallised from chloroform as soft colourless plates of N-methyl-1-(4-isopropylphenyl) ethylammonium perfluoro-octylsulphonate (60 g). (Found: C 33.05; H 2.43; N 2.09%. C20H20F17NO3S requires: C 35.4; H 2.98; N 2.07%).

후처리

  1. customThe ethanol solution was evaporated under reduced pressure
  2. customthe solid residue was recrystallised from chloroform as soft colourless plates of N-methyl-1-(4-isopropylphenyl) ethylammonium perfluoro-octylsulphonate (60 g)

출처 및 근거

ORD 기록
ord-ae36ff88a8234e78be35d23f84e3e4f6
출처 데이터셋
uspto-grants-1982_09
특허 번호
US04350644

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