Diphenyl Ether → HCID 13548681, 화합물

반응식

C([O:3][C:4](=O)[NH:5][N:6]=[CH:7][C:8]1[N:9]=[C:10]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[NH:11][C:12]=1[CH3:13])C.C1(OC2C=CC=CC=2)C=CC=CC=1>>[CH3:13][C:12]1[N:11]=[C:10]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[N:9]2[C:8]=1[CH:7]=[N:6][NH:5][C:4]2=[O:3]

참가 물질

반응물 2

HCID 7583Diphenyl Ether

HCID 136138544HCID 136138544, 화합물

생성물 1

HCID 13548681HCID 13548681, 화합물

실험 절차

An 8.33 gm. portion of 3-[(5-methyl-2-phenyl-4-imidazolyl)methylene]carbazic acid ethyl ester in 60 ml. of diphenyl ether is heated in an oil bath at 215°-230° C. for 20 minutes. The reaction mixture is diluted to 400 ml. with petroleum ether. The precipitate is collected and recrystallized from 350 ml. of benzene giving the desired product, m.p. 182°-184.5° C.

후처리

additionThe reaction mixture is diluted to 400 ml
customThe precipitate is collected
customrecrystallized from 350 ml

출처 및 근거

ORD 기록: ord-bd68faf660064b3f9941d962b113f693
출처 데이터셋: uspto-grants-1978_11
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04124766

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