Water → HCID 22760978, 화합물

HRID 1703973노트

반응식

HRID 1703973 반응식
[O:1]=[C:2]1[CH2:20][CH2:19][C:5]2[C:6]3[CH:18]=[CH:17][CH:16]=[CH:15][C:7]=3[O:8][C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=3[C:4]=2[CH2:3]1.[H-].[Al+3].[Li+].[H-].[H-].[H-].O>CCOCC>[OH:1][CH:2]1[CH2:20][CH2:19][C:5]2[C:6]3[CH:18]=[CH:17][CH:16]=[CH:15][C:7]=3[O:8][C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=3[C:4]=2[CH2:3]1

참가 물질

5

반응물 3

HCID 962WaterHCID 21226445Aluminium lithium hydrideHCID 22760937HCID 22760937, 화합물

생성물 1

HCID 22760978HCID 22760978, 화합물

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

6.2 g of 2-keto-1,2,3,4-tetrahydro-tribenzo(b,d,f)-oxepine are added to a suspension of 3.7 g of lithiumaluminiumhydride in 300 ml of dry ether. After refluxing for 2 hours 14.8 ml of water are added carefully. The suspension obtained is filtered off and after that the filtrate is dried and evaporated to dryness.

후처리

  1. additionare added carefully
  2. customThe suspension obtained
  3. filtrationis filtered off
  4. customafter that the filtrate is dried
  5. customevaporated to dryness

출처 및 근거

ORD 기록
ord-68cde95075704ef5a6e83ded9e89eba2
출처 데이터셋
uspto-grants-1978_11
특허 번호
US04125718

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