2-Octanol → Propan-2-yl 2-dodecylbenzene-1-sulfonate

HRID 1707313

반응식

HRID 1707313 반응식
CC(O)CCCCCC.[CH2:10]([C:22]1C=CC=C[C:23]=1S(Cl)(=O)=O)[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]CC.[C:32]1(C)[CH:37]=[CH:36][C:35]([S:38]([O:41][CH:42]([CH3:49])[CH2:43]CCCCC)(=[O:40])=[O:39])=[CH:34][CH:33]=1>>[CH2:19]([C:34]1[CH:33]=[CH:32][CH:37]=[CH:36][C:35]=1[S:38]([O:41][CH:42]([CH3:43])[CH3:49])(=[O:39])=[O:40])[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:22][CH3:23]

참가 물질

4

반응물 3

HCID 200832-OctanolHCID 3912199HCID 3912199, 화합물HCID 204390012-Dodecylbenzene-1-sulfonyl chloride

생성물 1

HCID 23368822Propan-2-yl 2-dodecylbenzene-1-sulfonate수율 83%

실험 절차

In Example of preparation of material 15, 2-octanol was used in place of 2-propanol in Example of preparation of material 14. In Example of preparation of material 16, dodecylbenzene sulfonyl chloride was used in place of p-toluene sulfonyl chloride in Example of preparation of material 14. Other procedures were made in the same way as Example of preparation of material 14. In Example of preparation of material 15, 1-methylheptyl p-toluenesulfonate was obtained in the yield of 72% and, in Example of preparation of material 16, 1-methylethyl dodecylbenzene sulfonate was obtained in the yield of 83%.

출처 및 근거

ORD 기록
ord-58dd63a5933b4544b12d862b35b14947
출처 데이터셋
uspto-grants-1994_10
특허 번호
US05352740

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