Acetone → Maleic Anhydride

HRID 1711799

반응식

HRID 1711799 반응식
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8].[C:9](O[O:18][C:19](=[O:26])[C:20]1C=CC=[CH:22][CH:21]=1)(=O)[C:10]1C=CC=CC=1.CC(C)=[O:29]>>[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH:9]=[CH2:10].[C:19]1(=[O:26])[O:18][C:22](=[O:29])[CH:21]=[CH:20]1

참가 물질

5

반응물 3

HCID 180AcetoneHCID 7187Benzoyl PeroxideHCID 194601,7-Octadiene

생성물 2

HCID 7923Maleic AnhydrideHCID 154391,9-Decadiene

실험 절차

This Example shows use alternative dienes to 1,7-octadiene. 1,9-decadiene (55.2 g, 0.40 mol) and maleic anhydride (19.6 g, 0.20 mol) in acetone (200 g) was polymerized in the same apparatus and under the same conditions as Example 4. The yield of desired copolymer was 33.2 g. The 1H NMR showed 17 mole % vinyl octyl protons, 15 mole % saturated octyl protons, and 4.3 mole % phenyl protons from the benzoyl peroxide initiator. Further characterization is presented in Table 2 and in FIG. 2, as discussed below.

출처 및 근거

ORD 기록
ord-41620c207db242b09507bc1997b8c2a6
출처 데이터셋
uspto-grants-2010_09
특허 번호
US07790822B2

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