2,3,5-Trifluorobenzyl bromide → 1,2,5-Trifluoro-3-methylbenzene

반응식

Br[CH2:2][C:3]1[CH:8]=[C:7]([F:9])[CH:6]=[C:5]([F:10])[C:4]=1[F:11].FC1C=C(C)C=C(F)C=1>>[F:10][C:5]1[CH:6]=[C:7]([F:9])[CH:8]=[C:3]([CH3:2])[C:4]=1[F:11]

참가 물질

반응물 2

HCID 27770522,3,5-Trifluorobenzyl bromide

HCID 27783293,5-Difluorotoluene

생성물 1

HCID 234469061,2,5-Trifluoro-3-methylbenzene

실험 절차

The title compound was prepared from 1-bromomethyl-2,3,5-trifluoro-benzene by a procedure analogous to that for 3,5-difluorotoluene, above. 1H NMR (400 MHz, CDCl3) δ ppm; MS (APCI, m/z): [M+H]+.

출처 및 근거

ORD 기록: ord-912a385f0477414f8785abbebd089254
출처 데이터셋: uspto-grants-2010_09
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07790902B2

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