Toluene → HCID 54399221, 화합물

HRID 1719573노트

반응식

HRID 1719573 반응식
[C:1]([C:5]1[CH:10]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[CH:8]=[C:7]([SH:15])[C:6]=1[OH:16])([CH3:4])([CH3:3])[CH3:2].[C:17]([O:21][CH3:22])(=[O:20])[CH:18]=[CH2:19].C1(C)C=CC=CC=1>C(N(CC)CC)C>[CH3:22][O:21][C:17](=[O:20])[CH2:18][CH2:19][S:15][C:7]1[CH:8]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[CH:10]=[C:5]([C:1]([CH3:4])([CH3:2])[CH3:3])[C:6]=1[OH:16]

참가 물질

5

반응물 3

HCID 1140TolueneHCID 7294Methyl AcrylateHCID 3041162Phenol, 2,2-bis(1,1-dimethylethyl)-6-mercapto-

생성물 1

HCID 54399221HCID 54399221, 화합물수율 57.5%

시약·촉매·용매 1

HCID 8471Triethylamine용매

실험 절차

In a 50 ml flask under nitrogen, a mixture of 5.00 grams of 2,4-di-tert-butyl-6-mercaptophenol, 1.80 grams of methyl acrylate and 20 mls toluene was treated with 0.50 mls of triethylamine. After stirring for three hours at ambient temperature, the solvent was removed in vacuo. The residue was purified by chromatography on silica gel using toluene/heptane eluent to give 3.90 g (57% yield) of a colorless oil.

후처리

  1. customthe solvent was removed in vacuo
  2. customThe residue was purified by chromatography on silica gel

출처 및 근거

ORD 기록
ord-eb1447d37e394e3080212b5acbb4ef17
출처 데이터셋
uspto-grants-1985_09
특허 번호
US04540732

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