Aniline → 2-oxo-N-phenylpropanehydrazonoyl chloride

HRID 1720237노트

반응식

HRID 1720237 반응식
[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[N:8]([O-])=O.[Na+].[Cl:12][CH:13](C(=O)C)[C:14](=[O:16])[CH3:15]>>[Cl:12][C:13](=[N:8][NH:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)[C:14](=[O:16])[CH3:15]

참가 물질

4

반응물 3

HCID 6115AnilineHCID 743283-Chloro-2,4-pentanedioneHCID 23668193Sodium Nitrite

생성물 1

HCID 27715222-oxo-N-phenylpropanehydrazonoyl chloride수율 40.3%

실험 절차

The reaction of 10.55 g (0.113 mol)of aminobenzene with 13.2 g of sodium nitrite and 20 g of 3-chloro-2,4-pentanedione as in Example 1 yielded 8.95 g of 1-chloro-1-[(phenyl)hydrazono]-2-propanone, mp 132°-134° C.

출처 및 근거

ORD 기록
ord-0de9b627fbae4f3f99c769040638639e
출처 데이터셋
uspto-grants-1996_04
특허 번호
US05506228

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