2-Methylbenzothiazole → HCID 20025798, 화합물

HRID 1723524노트

반응식

HRID 1723524 반응식
[Cl:1][CH2:2][CH2:3][CH2:4][CH2:5][O:6][C:7]1[CH:14]=[CH:13][CH:12]=[CH:11][C:8]=1[CH:9]=O.[CH3:15][C:16]1[S:17][C:18]2[CH:24]=[CH:23][CH:22]=[CH:21][C:19]=2[N:20]=1>>[Cl:1][CH2:2][CH2:3][CH2:4][CH2:5][O:6][C:7]1[CH:14]=[CH:13][CH:12]=[CH:11][C:8]=1/[CH:9]=[CH:15]/[C:16]1[S:17][C:18]2[CH:24]=[CH:23][CH:22]=[CH:21][C:19]=2[N:20]=1

참가 물질

3

반응물 2

HCID 84462-MethylbenzothiazoleHCID 137680584-Chlorobutoxybenzaldehyde

생성물 1

HCID 20025798HCID 20025798, 화합물수율 63%

실험 절차

The procedure of Example 18 was followed starting with 4-chlorobutoxybenzaldehyde (10 g, 47 mmol) and using 2-methylbenzothiazole (6.0 ml, 47 mmol) in place of 2-methylbenzoxazole to give 10.1 g (63% yield) of (E)-2-[2-(4-chlorobutoxyphenyl)ethenyl]benzothiazole (H) as a solid, mp 98°-100° C. 1H NMR (CDCl3): δ 8.01-6.89 (m, 10H), 4.01 (t, J=5.2 Hz, 2H), 3.61 (t, J=5.2 Hz, 2H), 1.94 (m, 4H).

출처 및 근거

ORD 기록
ord-1c13e99804c74eb3b3ba7365906b8d9e
출처 데이터셋
uspto-grants-1989_08
특허 번호
US04861897

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