2,4-Dihydroxy-3-allylbenzophenone → (2,4-Dihydroxy-3-propylphenyl)(phenyl)methanone

HRID 1727283노트

반응식

HRID 1727283 반응식
[OH:1][C:2]1[C:15]([CH2:16][CH:17]=[CH2:18])=[C:14]([OH:19])[CH:13]=[CH:12][C:3]=1[C:4]([C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)=[O:5]>C(OCC)(=O)C.[Pd]>[OH:1][C:2]1[C:15]([CH2:16][CH2:17][CH3:18])=[C:14]([OH:19])[CH:13]=[CH:12][C:3]=1[C:4]([C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)=[O:5]

참가 물질

4

반응물 1

HCID 219109812,4-Dihydroxy-3-allylbenzophenone

생성물 1

HCID 13019373(2,4-Dihydroxy-3-propylphenyl)(phenyl)methanone

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 8857Ethyl Acetate용매

실험 절차

A solution of 2,4-dihydroxy-3-(2-propenyl)benzophenone (3 g) was reduced under ˜1 atm H2 in ethyl acetate (100 mL) over 10% Pd/C catalyst (0.3 grams) for 3 hours. The product was purified by crystallization from methanol/water. The product is obtained as small yellow plates.

후처리

  1. customThe product was purified by crystallization from methanol/water
  2. customThe product is obtained as small yellow plates

출처 및 근거

ORD 기록
ord-de268f8f414d4757a863a9b72dc3d063
출처 데이터셋
uspto-grants-2009_02
특허 번호
US07495020B2

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