Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
(+-)-2-Undecanol → 2-Methanesulfonyloxyundecane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | (+-)-2-Undecanol | HCID 15448 | — |
| 반응물 | Methanesulfonyl chloride | HCID 31297 | — |
| 반응물 | Diisopropylethylamine | HCID 81531 | — |
| 반응물 | Decan-2-yl methanesulfonate | HCID 14916009 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 2-Methanesulfonyloxyundecane | HCID 15343316 | 95% |
반응 단계
2-Methanesulfonyloxyundecane was prepared as described for 2-methanesulfonyloxydecane from 2-undecanol (30.0 ml, 144 mmol), methanesulfonylchloride (15.5 ml, 200 mmol) and diisopropylethylamine (30.8 ml, 177 mmol) in dry CH2Cl2 (240 ml). After stirring for 3.5 hrs, the reaction was processed as previously stated but at 4 times the volumes to provide 2-methanesulfonyloxyundecane (31.35 g, 95%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05326553 |
| 출처 데이터셋 | uspto-grants-1994_07 |
| ORD ID | ord-2389d1d0164c45bb9b0646f32866c50e |
| 출처 메모 | uspto-grants-1994_07 |